赵孟頫是一位道教徒，曾受洞诀于茅山刘真人，一生书写道教经书无数。据文献记载，赵孟頫多次以小楷书《道德经》，现在能见到的，有墨迹本，也有刻本。有记载的刻本就包括元"茅绍之本"、明"墨池堂本"以及清"安素轩"本。
本书所刊为赵孟頫小楷《道德经》墨迹本，乌丝界栏，纵二十四点五厘米，横六百一十八厘米，卷首绘老子像，款署"延祐三年，岁在丙辰三月廿四五日，为进之高士书于松雪斋，孟頫"，现藏于故宫博物院。从款署可知赵孟頫在三月廿四、廿五两日，写完了五千余言的道德经全文。整幅作品点画精到，灵秀飘逸，姿态绰约，流美潇洒，洋洋数千言无一懈笔。难怪鲜于枢称道赵孟頫："子昂篆隶正行颠草为当代，而小楷又为子昂诸书。"
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